IndiumV3, Chine, Analysis, bibRecord, 000C47

A New Dithienylbenzotriazole-Based Poly(2,7-carbazole) for Efficient Photovoltaics

Identifieur interne : 000C47 ( Chine/Analysis ); précédent : 000C46; suivant : 000C48

A New Dithienylbenzotriazole-Based Poly(2,7-carbazole) for Efficient Photovoltaics

Auteurs : RBID : Pascal:10-0489170

Descripteurs français

Pascal (Inist)
- Thiophène copolymère, Carbazole dérivé copolymère, Copolymère hétérocyclique azote, Copolymère aromatique, Copolymère conjugué, Terpolymère, Composé soluble, Préparation, Polycondensation solution, Copulation Suzuki, Propriété électrochimique, Absorption optique, Photoluminescence, Mobilité trou, Stabilité thermique, Mélange binaire, Composé du fullerène, Cellule solaire organique, Topographie surface, Tension circuit ouvert, Courant court circuit, Facteur remplissage, Effet composition, Etude expérimentale, Benzotriazole dérivé copolymère, Carbazolylène(9-[1-octylnonyl]) copolymère.

English descriptors

KwdEn :
- Aromatic copolymer, Binary mixture, Carbazole derivative copolymer, Composition effect, Conjugated copolymer, Electrochemical properties, Experimental study, Fill factor, Fullerene compounds, Hole mobility, Nitrogen heterocycle copolymer, Open circuit voltage, Optical absorption, Organic solar cells, Photoluminescence, Preparation, Short circuit currents, Soluble compound, Solution polycondensation, Surface topography, Suzuki coupling, Terpolymer, Thermal stability, Thiophene copolymer.

Abstract

A new dithienyl benzotriazole-based conjugated polymer was synthesized by Suzuki coupling reaction. The polymer was found to be soluble in common organic solvents, such as chloroform, tetrahydrofuran and chlorobenzene, with excellent film-forming properties. The structure of the polymer was confirmed by ¹H NMR, the molecular weights determined by GPC and the thermal properties investigated by TGA and DSC. The polymer films exhibited an absorption band in the wavelength range 300 to 610 nm. Preliminary photovoltaic cells based on the composite structure of indium tin oxide (ITO)/PEDOT:PSS/PCDTBTz:PC₆₀BM (1:2 w/w)/ Al showed an open-circuit voltage of 0.92 V, a power conversion efficiency of 2.2% and a short circuit current of 5.33 mA cm^-2.

Links toward previous steps (curation, corpus...)

to stream Main, to step Corpus: 003B23
to stream Main, to step Repository: 004793
to stream Chine, to step Extraction: 000C47

Links to Exploration step

Pascal:10-0489170

Le document en format XML

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<author><name sortKey="Najari, Ahmed" uniqKey="Najari A">Ahmed Najari</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Département de Chimie, Université Laval</s1>
<s2>Quebec City, G1K 7P4</s2>
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<author><name>BO LIU</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>College of Chemistry and Chemical Engineering, Central South University</s1>
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<author><name sortKey="Berrouard, Philippe" uniqKey="Berrouard P">Philippe Berrouard</name>
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</author>
<author><name sortKey="Gendron, David" uniqKey="Gendron D">David Gendron</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Département de Chimie, Université Laval</s1>
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</author>
<author><name>YUEHUI HE</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>College of Chemistry and Chemical Engineering, Central South University</s1>
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<author><name>KECHAO ZHOU</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>State Key Laboratory for Powder Metallurgy, Central South University</s1>
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</author>
<author><name sortKey="Leclerc, Mario" uniqKey="Leclerc M">Mario Leclerc</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Département de Chimie, Université Laval</s1>
<s2>Quebec City, G1K 7P4</s2>
<s3>CAN</s3>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>8 aut.</sZ>
</inist:fA14>
<country>Canada</country>
<wicri:noRegion>Quebec City, G1K 7P4</wicri:noRegion>
</affiliation>
</author>
<author><name>YINGPING ZOU</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>State Key Laboratory for Powder Metallurgy, Central South University</s1>
<s2>Changsha 410083</s2>
<s3>CHN</s3>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
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<date when="2010">2010</date>
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<idno type="RBID">Pascal:10-0489170</idno>
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<seriesStmt><idno type="ISSN">1022-1352</idno>
<title level="j" type="abbreviated">Macromol. chem. phys. : (Print)</title>
<title level="j" type="main">Macromolecular chemistry and physics : (Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aromatic copolymer</term>
<term>Binary mixture</term>
<term>Carbazole derivative copolymer</term>
<term>Composition effect</term>
<term>Conjugated copolymer</term>
<term>Electrochemical properties</term>
<term>Experimental study</term>
<term>Fill factor</term>
<term>Fullerene compounds</term>
<term>Hole mobility</term>
<term>Nitrogen heterocycle copolymer</term>
<term>Open circuit voltage</term>
<term>Optical absorption</term>
<term>Organic solar cells</term>
<term>Photoluminescence</term>
<term>Preparation</term>
<term>Short circuit currents</term>
<term>Soluble compound</term>
<term>Solution polycondensation</term>
<term>Surface topography</term>
<term>Suzuki coupling</term>
<term>Terpolymer</term>
<term>Thermal stability</term>
<term>Thiophene copolymer</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Thiophène copolymère</term>
<term>Carbazole dérivé copolymère</term>
<term>Copolymère hétérocyclique azote</term>
<term>Copolymère aromatique</term>
<term>Copolymère conjugué</term>
<term>Terpolymère</term>
<term>Composé soluble</term>
<term>Préparation</term>
<term>Polycondensation solution</term>
<term>Copulation Suzuki</term>
<term>Propriété électrochimique</term>
<term>Absorption optique</term>
<term>Photoluminescence</term>
<term>Mobilité trou</term>
<term>Stabilité thermique</term>
<term>Mélange binaire</term>
<term>Composé du fullerène</term>
<term>Cellule solaire organique</term>
<term>Topographie surface</term>
<term>Tension circuit ouvert</term>
<term>Courant court circuit</term>
<term>Facteur remplissage</term>
<term>Effet composition</term>
<term>Etude expérimentale</term>
<term>Benzotriazole dérivé copolymère</term>
<term>Carbazolylène(9-[1-octylnonyl]) copolymère</term>
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<front><div type="abstract" xml:lang="en">A new dithienyl benzotriazole-based conjugated polymer was synthesized by Suzuki coupling reaction. The polymer was found to be soluble in common organic solvents, such as chloroform, tetrahydrofuran and chlorobenzene, with excellent film-forming properties. The structure of the polymer was confirmed by <sup>1</sup>
H NMR, the molecular weights determined by GPC and the thermal properties investigated by TGA and DSC. The polymer films exhibited an absorption band in the wavelength range 300 to 610 nm. Preliminary photovoltaic cells based on the composite structure of indium tin oxide (ITO)/PEDOT:PSS/PCDTBTz:PC<sub>60</sub>
BM (1:2 w/w)/ Al showed an open-circuit voltage of 0.92 V, a power conversion efficiency of 2.2% and a short circuit current of 5.33 mA cm<sup>-2</sup>
.</div>
</front>
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<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1022-1352</s0>
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<fA03 i2="1"><s0>Macromol. chem. phys. : (Print)</s0>
</fA03>
<fA05><s2>211</s2>
</fA05>
<fA06><s2>18</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>A New Dithienylbenzotriazole-Based Poly(2,7-carbazole) for Efficient Photovoltaics</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>BO PENG</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>NAJARI (Ahmed)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>BO LIU</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>BERROUARD (Philippe)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>GENDRON (David)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>YUEHUI HE</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>KECHAO ZHOU</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>LECLERC (Mario)</s1>
</fA11>
<fA11 i1="09" i2="1"><s1>YINGPING ZOU</s1>
</fA11>
<fA14 i1="01"><s1>College of Chemistry and Chemical Engineering, Central South University</s1>
<s2>Changsha 410083</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>6 aut.</sZ>
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<s2>Quebec City, G1K 7P4</s2>
<s3>CAN</s3>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>8 aut.</sZ>
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<fA14 i1="03"><s1>State Key Laboratory for Powder Metallurgy, Central South University</s1>
<s2>Changsha 410083</s2>
<s3>CHN</s3>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
<sZ>9 aut.</sZ>
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<fA20><s1>2026-2033</s1>
</fA20>
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</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>4111</s2>
<s5>354000192639540100</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2010 INIST-CNRS. All rights reserved.</s1>
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<fA45><s0>16 ref.</s0>
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<fA47 i1="01" i2="1"><s0>10-0489170</s0>
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<fA60><s1>P</s1>
</fA60>
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</fA64>
<fA66 i1="01"><s0>DEU</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>A new dithienyl benzotriazole-based conjugated polymer was synthesized by Suzuki coupling reaction. The polymer was found to be soluble in common organic solvents, such as chloroform, tetrahydrofuran and chlorobenzene, with excellent film-forming properties. The structure of the polymer was confirmed by <sup>1</sup>
H NMR, the molecular weights determined by GPC and the thermal properties investigated by TGA and DSC. The polymer films exhibited an absorption band in the wavelength range 300 to 610 nm. Preliminary photovoltaic cells based on the composite structure of indium tin oxide (ITO)/PEDOT:PSS/PCDTBTz:PC<sub>60</sub>
BM (1:2 w/w)/ Al showed an open-circuit voltage of 0.92 V, a power conversion efficiency of 2.2% and a short circuit current of 5.33 mA cm<sup>-2</sup>
.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D09D02E</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>001D06C02D1</s0>
</fC02>
<fC02 i1="03" i2="X"><s0>230</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Thiophène copolymère</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Thiophene copolymer</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Tiofeno copolímero</s0>
<s2>NK</s2>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Carbazole dérivé copolymère</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Carbazole derivative copolymer</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Carbazol derivado copolímero</s0>
<s2>NK</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Copolymère hétérocyclique azote</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Nitrogen heterocycle copolymer</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Copolímero heterocíclico nitrógeno</s0>
<s2>NK</s2>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Copolymère aromatique</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Aromatic copolymer</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Copolímero aromático</s0>
<s2>NK</s2>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Copolymère conjugué</s0>
<s2>NK</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Conjugated copolymer</s0>
<s2>NK</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Copolímero conjugado</s0>
<s2>NK</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Terpolymère</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Terpolymer</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Terpolímero</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Composé soluble</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Soluble compound</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Compuesto soluble</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Préparation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Preparation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Preparación</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Polycondensation solution</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Solution polycondensation</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Policondensación solución</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Copulation Suzuki</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Suzuki coupling</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Suzuki copulación</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Propriété électrochimique</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Electrochemical properties</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Propiedad electroquímica</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Absorption optique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Optical absorption</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Absorción óptica</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Photoluminescence</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Photoluminescence</s0>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Fotoluminiscencia</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Mobilité trou</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Hole mobility</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Movilidad agujero</s0>
<s5>17</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Stabilité thermique</s0>
<s5>18</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Thermal stability</s0>
<s5>18</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Estabilidad térmica</s0>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Mélange binaire</s0>
<s5>19</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Binary mixture</s0>
<s5>19</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Mezcla binaria</s0>
<s5>19</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Composé du fullerène</s0>
<s5>20</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG"><s0>Fullerene compounds</s0>
<s5>20</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>Cellule solaire organique</s0>
<s5>21</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG"><s0>Organic solar cells</s0>
<s5>21</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Topographie surface</s0>
<s5>22</s5>
</fC03>
<fC03 i1="19" i2="3" l="ENG"><s0>Surface topography</s0>
<s5>22</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Tension circuit ouvert</s0>
<s5>23</s5>
</fC03>
<fC03 i1="20" i2="3" l="ENG"><s0>Open circuit voltage</s0>
<s5>23</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>Courant court circuit</s0>
<s5>24</s5>
</fC03>
<fC03 i1="21" i2="3" l="ENG"><s0>Short circuit currents</s0>
<s5>24</s5>
</fC03>
<fC03 i1="22" i2="3" l="FRE"><s0>Facteur remplissage</s0>
<s5>25</s5>
</fC03>
<fC03 i1="22" i2="3" l="ENG"><s0>Fill factor</s0>
<s5>25</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE"><s0>Effet composition</s0>
<s5>26</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG"><s0>Composition effect</s0>
<s5>26</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA"><s0>Efecto composición</s0>
<s5>26</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>27</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>27</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>27</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE"><s0>Benzotriazole dérivé copolymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>32</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE"><s0>Carbazolylène(9-[1-octylnonyl]) copolymère</s0>
<s2>NK</s2>
<s4>INC</s4>
<s5>33</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Propriété optique</s0>
<s5>13</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Optical properties</s0>
<s5>13</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Propiedad óptica</s0>
<s5>13</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE"><s0>Propriété électrique</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="X" l="ENG"><s0>Electrical properties</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA"><s0>Propiedad eléctrica</s0>
<s5>16</s5>
</fC07>
<fN21><s1>326</s1>
</fN21>
<fN44 i1="01"><s1>PSI</s1>
</fN44>
<fN82><s1>PSI</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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   |wiki=   *** parameter Area/wikiCode missing *** 
   |area=    IndiumV3
   |flux=    Chine
   |étape=   Analysis
   |type=    RBID
   |clé=     Pascal:10-0489170
   |texte=   A New Dithienylbenzotriazole-Based Poly(2,7-carbazole) for Efficient Photovoltaics
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A New Dithienylbenzotriazole-Based Poly(2,7-carbazole) for Efficient Photovoltaics

A New Dithienylbenzotriazole-Based Poly(2,7-carbazole) for Efficient Photovoltaics

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